Platinum on 2-aminoethanethiol functionalized MIL-101 as a catalyst for alkene hydrosilylation
نویسندگان
چکیده
منابع مشابه
Amine-functionalized MIL-101(Cr) with imbedded platinum nanoparticles as a durable photocatalyst for hydrogen production from water.
The incorporation of Pt nanoparticles into a highly stable and porous amine-functionalized MIL-101(Cr) was performed for construction of a visible light driven H2 evolution system with high activity and strong stability.
متن کاملPlatinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation.
Colloidal suspensions of monodisperse platinum nanoparticles of 2 nm diameter have been used to catalyze the hydrosilylation of 1-octene with a polymethylhydrosiloxane. The nanoparticles were found to be as efficient as Karstedt's complex, showing that colloid formation from homogeneous species during hydrosilylation reactions is not necessarily a deactivation pathway. These results also reacti...
متن کاملAn Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes.
The first efficient and non-precious nanoparticle catalyst for alkene hydrosilylation with commercially relevant tertiary silanes has been developed. The nickel nanoparticle catalyst was prepared in situ from a simple nickel alkoxide precatalyst Ni(O(t) Bu)2 ⋅x KCl. The catalyst exhibits high activity for anti-Markovnikov hydrosilylation of unactivated terminal alkenes and isomerizing hydrosily...
متن کامل[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones.
The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.
متن کاملCatalytic properties of MIL-101.
A very high catalytic activity in the cyanosilylation reaction was observed for MIL-101, a chromium based metal-organic framework; moreover, MIL-101 is also a remarkably stable support for palladium in hydrogenation reactions, with significantly higher activity than e.g. palladium on activated carbon.
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2019
ISSN: 2046-2069
DOI: 10.1039/c9ra01408j